| 摘要: |
| 为了优化反应条件及提高催化剂的反应效率,从热力学角度对甲烷三重整的反应过程进行了分析,求出了平衡常数与温度的关系式,据此对重整过程中各反应的竞争能力进行了比较。研究了反应温度、压力对重整结果的影响。利用Aspen Plus软件采用排列组合的方法,求出了1 331种不同进料比下CH4、CO2转化率、n(H2)/n(CO)、积碳量及反应器热负荷的值,并进行了筛选。结果 表明,升温有利于CH4和CO2的转化,但压力升高不利于反应的正向进行,从而确定了最佳反应温度和压力分别为1 123.15 K和101.325 kPa。在此条件下,当n(CH4)∶n(CO2)∶n(H2O)∶n(O2)为1∶0.2∶0.1∶0.5时,积碳量为零且系统能够实现自热。此时,CH4和CO2的转化率分别为99.35%和46.98%,n(H2)/n(CO)=1.73。 |
| 关键词: 甲烷 重整 热力学 Aspen Plus 零积碳 自热 |
| DOI：10.3969/j.issn.1007-3426.2015.06.010 |
| 分类号:TE624.3 |
| 基金项目:国土资源部煤炭资源勘查与综合利用重点实验室科研课题“基于煤灰熔融粘温特性的气化操作工况调优辅助系统开发”(KF2013-1)。 |
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| Thermodynamic simulation of methane tri-reforming based on Aspen Plus |
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Li Jianwei,Chen Chong,Zhang Sanli,Yao Weiguo,Xue Hui
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(College of Chemistry and Chemical Engineering, Xi′an University of Science and Technology, Xi′an 710054, China)
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| Abstract: |
| To optimize reaction conditions and improve the efficiency of catalyst, the reaction process is analyzed on methane tri-reforming by thermodynamic, the relationship between the equilibrium constant and the temperature is calculated, also the competition abilities of the reactions in the reforming process are compared. The influences of reaction temperature and pressure on the reforming characteristics are studied as well. The CH4 and CO2 conversion ratio, H2/CO ratio and reactor heat duty of 1 331 different feed ratios are calculated by using Aspen Plus analysis. The results show that the conversion rate increases with temperature and decreases with pressure, so the optimum reaction temperature and pressure are 1 123.15 K and 101.325 kPa respectively. Under this condition, with the mole ratio of CH4∶CO2∶H2O∶O2 being 1∶0.2∶0.1∶0.5 in the feed gases, the reforming system can realize self-heating avoiding carbon deposition on catalyst. At this time, CH4 and CO2 conversion rate reach 99.35% and 46.98% respectively, the product gas with a H2/CO ratio of 1.73. |
| Key words: methane reforming thermodynamics Aspen Plus zero carbon deposition auto-therma |
