引用本文:娄少华,钱永康. 管式反应炉制取二硫化碳反应的研究[J]. 石油与天然气化工, 2011, 40(1): 18-21,7,8.
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管式反应炉制取二硫化碳反应的研究
娄少华, 钱永康
北京航天动力研究所
摘要:
本文依据甲烷与硫磺反应生成二硫化碳的相关数据,由化学反应动力学理论计算出硫磺分解的动力学数据,得到包括6个主要反应机理的计算模型。利用计算流体力学软件FLU-ENT对生成二硫化碳的反应进行模拟计算,寻找影响二硫化碳产率的因素,从而对管式反应器的设计和优化等提供理论依据。
关键词:  二硫化碳  反应机理  管式反应炉  优化
DOI:
分类号:TQ116.3
基金项目:
Study on Carbon Disulfide Reaction in Tubular Reacting Furnace
Lou Shaohua, Qian Yongkang
Beijing Aerospace Pro-pulsion Institute
Abstract:
In the paper,six main reactions are summarized to form the mathematics model,according to thecorrelative data analysis of methane reacting with sulfur and sulfur molecule decomposition. The reaction process was simulated and calculated with Fluent hydrodynamic software and the influential factors on carbon disulfide productive ratewould be found out,the reaction process is simulated by the hydrodynamic software of Fluent,which will provide theoretical basis for design and optimization of tubular reacting furnace.
Key words:  carbon disulfide  reaction mechanism  tubular reacting furnace  optimization