引用本文:邬元月,石善志,黄建波,于会永,董宝军,曾德智. 含CO2高温蒸汽环境中低合金钢耐腐蚀性能评价[J]. 石油与天然气化工, 2017, 46(4): 77-81.
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含CO2高温蒸汽环境中低合金钢耐腐蚀性能评价
邬元月1,石善志1,黄建波1,于会永1,董宝军2,曾德智2
1.中国石油新疆油田分公司工程技术研究院;2.油气藏地质及开发工程国家重点实验室·西南石油大学
摘要:
利用高温高压釜模拟CO2辅助蒸汽驱注气井筒工况,在CO2分压为2 MPa,温度为160~220 ℃条件下,对低合金钢进行了失重挂片腐蚀试验,得到了不同温度条件下管材的腐蚀速率,并利用扫描电镜和能谱仪观测管材在不同温度条件下的腐蚀形貌及产物组成。实验结果表明:在160~220 ℃范围内,随着温度的升高,低合金钢的腐蚀速率呈现先降低后增大的变化趋势,且均在160 ℃时腐蚀速率最高;在实验条件下,两种低合金碳钢的均匀腐蚀速率均小于油田控制指标0.076mm/a,满足注气井井筒管柱的腐蚀控制要求。 
关键词:  蒸汽驱  CO2腐蚀  温度  油套管钢  腐蚀速率 
DOI:10.3969/j.issn.1007-3426.2017.04.015
分类号:
基金项目:
Evaluation of corrosion resistance for low alloy steels in high temperature steam environment with CO2
Wu Yuanyue1, Shi Shanzhi1, Huang Jianbo1, Yu Huiyong1, Dong Baojun2, Zeng Dezhi2
1. Research Institute of Engineering Technology, PetroChina Xinjiang Oilfield Company, Karamay, Xinjiang, China;2. State Key Laboratory of Oil & Gas Reservoir Geology and Exploitation (Southwest Petroleum University), Chengdu, Sichuan, China
Abstract:
By simulating the environment of CO2 auxiliary steam with HTHP autoclave, the corrosion behavior of low alloy steels was studied under 160-220 ℃ and 2 MPa partial pressure, and the corrosion rate was measured by the weight loss method. The morphology and composition of the corrosion product under different temperature were analyzed by SEM and EDS. The results showed that the average corrosion rate of N80 and 3Cr steels appeared as a deep ‘V’ shape. The corrosion of N80 and 3Cr steel reached the maximum when the temperature was 160 ℃. Under the test conditions, the uniform corrosion rates of two low alloy steels were less than the control target of oil field (0.076 mm/a), and both met the demand of gas injection well.
Key words:  steam drive  CO2 corrosion  temperature  well tube steel  corrosion rate